Title: Transformation mechanism of different chemically precipitated apatitic precursors into beta-tricalcium phosphate upon calcination
Authors: Liou, SC
Chen, SY
材料科學與工程學系
Department of Materials Science and Engineering
Keywords: Ca-deficient apatite;beta-tricalcium phosphate;JMA equation;transformation kinetics
Issue Date: 1-Dec-2002
Abstract: The Ca-deficient apatite (CDHA) was prepared from the precursors of (CH3COO)(2)Ca - xH(2)O, Ca(NO3)(2).4H(2)O and H3PO4, (NH4)H2PO4 to investigate the transformation mechanism of beta-tricalcium phosphate (beta-TCP). X-ray diffraction analysis shows that the development of beta-TCP is not via direct reaction between Ca and P for all the different combinations between Ca and P precursors. The activation energy of beta-TCP formation with (NH4)H2PO4 as precursor was higher than that with H3PO4. Following the Johnson-Mehl-Avrami equation, the reaction kinetics of beta-TCP phase formation is found one-dimension growth with interface-controlled and diffusion controlled growth depending on the annealing temperature. There exists a transition between 750 degreesC and 825 degreesC, and the transition rate from interface-controlled to diffusion-controlled growth is precursor-dependent. (C) 2002 Elsevier Science Ltd. All rights reserved.
URI: http://dx.doi.org/10.1016/S0142-9612(02)00198-9
http://hdl.handle.net/11536/28346
ISSN: 0142-9612
DOI: 10.1016/S0142-9612(02)00198-9
Journal: BIOMATERIALS
Volume: 23
Issue: 23
Begin Page: 4541
End Page: 4547
Appears in Collections:Articles


Files in This Item:

  1. 000178116900013.pdf

If it is a zip file, please download the file and unzip it, then open index.html in a browser to view the full text content.