完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.author | Kuo, SW | en_US |
dc.contributor.author | Lin, CL | en_US |
dc.contributor.author | Chang, FC | en_US |
dc.date.accessioned | 2014-12-08T15:42:19Z | - |
dc.date.available | 2014-12-08T15:42:19Z | - |
dc.date.issued | 2002-06-01 | en_US |
dc.identifier.issn | 0032-3861 | en_US |
dc.identifier.uri | http://dx.doi.org/10.1016/S0032-3861(02)00214-8 | en_US |
dc.identifier.uri | http://hdl.handle.net/11536/28741 | - |
dc.description.abstract | The hydrogen bonding and miscibility behaviors of poly(2-vinylpyridine) (P2VP) or poly(4-vinylpyridine) (P4VP) with phenolic resin were investigated by differential scanning calorimetry and Fourier transform infrared spectroscopy (FTIR). These blends have a single glass transition over the entire composition range indicating that these blends are able to form a miscible phase due to the formation of intermolecular hydrogen bonding between hydroxyl of phenolic and pyridine ring of poly (vinylpyridines). Furthermore, FTIR studies on the hydrogen-bonding interaction between the hydroxyl group of phenolic and pyridine ring of poly (vinylpyridines) at various compositions and temperatures indicate that the greater inter-association for P4VP than P2VP due to the steric hindrance effect on specific interaction between these two polymers. Finally, inter-association equilibrium constants of phenolic/P2VP and phenolic/P4VP blends were determined by model compounds. (C) 2002 Elsevier Science Ltd. All rights reserved. | en_US |
dc.language.iso | en_US | en_US |
dc.subject | hydrogen bonding | en_US |
dc.subject | steric hindrances | en_US |
dc.subject | effect polymer blend | en_US |
dc.title | The study of hydrogen bonding and miscibility in poly (vinylpyridines) with phenolic resin | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1016/S0032-3861(02)00214-8 | en_US |
dc.identifier.journal | POLYMER | en_US |
dc.citation.volume | 43 | en_US |
dc.citation.issue | 14 | en_US |
dc.citation.spage | 3943 | en_US |
dc.citation.epage | 3949 | en_US |
dc.contributor.department | 應用化學系 | zh_TW |
dc.contributor.department | Department of Applied Chemistry | en_US |
dc.identifier.wosnumber | WOS:000176030500012 | - |
dc.citation.woscount | 51 | - |
顯示於類別: | 期刊論文 |