Synthesis of diacetal trioxa-cage compounds via reaction of bicycle [2.2.1]heptenes and bicyclo[2.2.2]octenes with dimethyldioxirane

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DC 欄位	值	語言
dc.contributor.author	Lin, HC	en_US
dc.contributor.author	Wu, HJ	en_US
dc.date.accessioned	2014-12-08T15:45:47Z	-
dc.date.available	2014-12-08T15:45:47Z	-
dc.date.issued	2000-01-14	en_US
dc.identifier.issn	0040-4020	en_US
dc.identifier.uri	http://hdl.handle.net/11536/30806	-
dc.description.abstract	A new entry for the synthesis of diacetal trioxa-cage compounds via oxirane-induced sequential cyclization reaction of 2,3-bis-endo-diacylbicyclo[2.2.1]-5-heptenes and 2,3-bis-endo-diacylbicyclo[2.2.2]-5-octenes is reported. In the case of bicyclo[2.2.2]octenes, sequential cyclization reaction induced by iodine as electrophile failed. We have also demonstrated that dimethyldioxirane can selectively oxidize hemiacetals to give lactones with the secondary hydroxy group intact. (C) 2000 Elsevier Science Ltd. All rights reserved.	en_US
dc.language.iso	en_US	en_US
dc.subject	dimethyldioxirane	en_US
dc.subject	diacetal trioxa-cage compounds	en_US
dc.subject	lactones	en_US
dc.title	Synthesis of diacetal trioxa-cage compounds via reaction of bicycle [2.2.1]heptenes and bicyclo[2.2.2]octenes with dimethyldioxirane	en_US
dc.type	Article	en_US
dc.identifier.journal	TETRAHEDRON	en_US
dc.citation.volume	56	en_US
dc.citation.issue	3	en_US
dc.citation.spage	341	en_US
dc.citation.epage	350	en_US
dc.contributor.department	應用化學系	zh_TW
dc.contributor.department	Department of Applied Chemistry	en_US
dc.identifier.wosnumber	WOS:000084896900001	-
dc.citation.woscount	10	-
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