完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.author | Hsiue, GH | en_US |
dc.contributor.author | Wang, WJ | en_US |
dc.contributor.author | Chang, FC | en_US |
dc.date.accessioned | 2014-12-08T15:46:18Z | - |
dc.date.available | 2014-12-08T15:46:18Z | - |
dc.date.issued | 1999-08-15 | en_US |
dc.identifier.issn | 0021-8995 | en_US |
dc.identifier.uri | http://hdl.handle.net/11536/31154 | - |
dc.identifier.uri | http://dx.doi.org/10.1002/(SICI)1097-4628(19990815)73:7<1231 | en_US |
dc.description.abstract | A new silicon-containing oxirane triglycidyl phenyl silane oxide (TGPSO) and its corresponding silicon-containing epoxy resins are synthesized and characterized. The activation energies of TGPSO curing reaction with various curing agents, including 4,4-diaminodiphenylmethane, 4,4-diaminodiphenylsulfone, and dicyanodiaminde, are found to be 180, 196.5, and 154 kJ/mol. The curing reaction of TGPSO with diamines is determined to be a first-order reaction through means of Arrhenius plots. The introduction of the silicon-containing group results in higher curing reactivity. This silicon-containing resin possesses higher char yield as well as higher limiting oxygen index (LOI = 35) than the commercial epoxy resins, confirming the usefulness of these silicon-containing epoxy resins as flame retardants. Char yields and LOI measurements demonstrate that incorporating silicon into epoxy resins is able to improve their flame retardancy. (C) 1999 John Wiley & Sons, Inc. | en_US |
dc.language.iso | en_US | en_US |
dc.subject | silicon | en_US |
dc.subject | epoxy | en_US |
dc.subject | char yield | en_US |
dc.subject | limiting oxygen index | en_US |
dc.title | Synthesis, characterization, thermal and flame-retardant properties of silicon-based epoxy resins | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1002/(SICI)1097-4628(19990815)73:7<1231 | en_US |
dc.identifier.journal | JOURNAL OF APPLIED POLYMER SCIENCE | en_US |
dc.citation.volume | 73 | en_US |
dc.citation.issue | 7 | en_US |
dc.citation.spage | 1231 | en_US |
dc.citation.epage | 1238 | en_US |
dc.contributor.department | 應用化學系 | zh_TW |
dc.contributor.department | Department of Applied Chemistry | en_US |
dc.identifier.wosnumber | WOS:000080550900018 | - |
dc.citation.woscount | 74 | - |
顯示於類別: | 期刊論文 |