標題: A stereoselective synthesis of platyphyllide
作者: Ho, TL
Ho, MF
應用化學系
Department of Applied Chemistry
公開日期: 7-七月-1999
摘要: The norsesquiterpene lactone, platyphyllide has been synthesized in 8 steps in 23% overall yield via the Diels-Alder adduct of 2-(4-methylpent-3-enyl)furan with dimethyl acetylenedicarboxylate, the 3-substituted phthalic diester, and an o-formylbenzamide. An intramolecular ene reaction established the skeleton, and the final step involved inversion of configuration at the benzylic site.
URI: http://dx.doi.org/10.1039/a902410g
http://hdl.handle.net/11536/31211
ISSN: 0300-922X
DOI: 10.1039/a902410g
期刊: JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
Volume: 
Issue: 13
起始頁: 1823
結束頁: 1826
顯示於類別:期刊論文


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