Hyperbranched poly(ether ketone) with carboxylic acid terminal groups: Synthesis, characterization, and derivatization

Abstract

A new procedure is described for the formation of a hyperbranched poly(ether ketone) with carboxylic acid terminal groups. This preparation was based on the one-step synthesis of an AB(2)-type monomer 5-phenoxyisophthalic acid using phosphorus pentoxide/methanesulfonic acid as the condensing agent and solvent. The electrophilic aromatic substitution reaction led to the formation of the al yl ketone linkage. With the help of model compounds, H-1 NMR studies revealed that the degree of branching of the poly(ether ketone) was about 55%. The terminated carboxylic acid groups were readily functionalized, yielding hyperbranched polymers with a variety of different functional chain ends. The nature of the chain ends was shown to dramatically affect physical properties of the hyperbranched macromolecules. The ammonium derivative was soluble in water and behaved as a unimolecular micelle.