標題: Crystallization in Unsaturated Glycine/D(2)O Solution Achieved by Irradiating a Focused Continuous Wave Near Infrared Laser
作者: Rungsimanon, Thitiporn
Yuyama, Ken-ichi
Sugiyama, Teruki
Masuhara, Hiroshi
應用化學系
應用化學系分子科學碩博班
Department of Applied Chemistry
Institute of Molecular science
公開日期: 1-Nov-2010
摘要: The crystallization of glycine in unsaturated solution is made possible by laser trapping of its molecular clusters due to photon pressure of a focused continuous wave near-infrared laser beam. Always one single crystal is spatiotemporally formed at a focal spot, and then it undergoes dissolution, eventually leading to repetitive crystallization and dissolution. The polymorph characterization of the crystal formed in unsaturated solution confirmed the gamma-form, which is not obtainable by conventional crystallization methods. The preparation probability of the gamma-form compared to the alpha-form is much higher than that in the supersaturated solution.
URI: http://dx.doi.org/10.1021/cg100830x
http://hdl.handle.net/11536/31969
ISSN: 1528-7483
DOI: 10.1021/cg100830x
期刊: CRYSTAL GROWTH & DESIGN
Volume: 10
Issue: 11
起始頁: 4686
結束頁: 4688
Appears in Collections:Articles