標題: Intense violet-blue-emitting Ba(2)AlB(4)O(9)Cl:Eu(2+) phosphors for applications in fluorescent lamps and ultraviolet-light-emitting diodes
作者: Kuo, Te-Wen
Huang, Chien-Hao
Chen, Teng-Ming
應用化學系
Department of Applied Chemistry
公開日期: 1-Aug-2010
摘要: We synthesized a violet-blue phosphor Ba(2)AlB(4)O(9)Cl:Eu(2+) with a solid-state reaction. The excitation and emission spectra of this phosphor showed that all were broadband due to 4f(7) - 4f(6)d(1) transitions of Eu(2+). The phosphors with different Eu(2+) concentrations presented violet-blue luminescence for ultraviolet [(UV) 250-390 nm] excitation. The optimum concentration of Eu(2+) in Ba(2)AlB(4)O(9)Cl:Eu(2+) is determined to be 6 mol.%. The luminous efficiency was found to be 8.1 lm/W for the violet-blue fluorescent lamp and 3.2 lm/W for the violet-blue phosphor-converted light-emitting diode, respectively. Ba(2)AlB(4)O(9)Cl:Eu(2+) would be a promising phosphor for converting the UV radiation to violet-blue emission for a novel high light-conversion efficiency phototherapy illuminator. (C) 2010 Optical Society of America
URI: http://dx.doi.org/10.1364/AO.49.004202
http://hdl.handle.net/11536/32346
ISSN: 0003-6935
DOI: 10.1364/AO.49.004202
期刊: APPLIED OPTICS
Volume: 49
Issue: 22
起始頁: 4202
結束頁: 4206
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