标题: | 碳簇化合物之合成与动力学探讨 Synthetic and Kinetic Studies of Fullerene Derivatives |
作者: | 赖立祥 Lai, Li-Hsiang 庄士卿 Chuang, Shih-Ching 应用化学系硕博士班 |
关键字: | 碳簇化合物;动力学;Fullerene;Kinetic |
公开日期: | 2009 |
摘要: | 本论文主要分为碳六十衍生物的合成与化学性质探讨以及碳簇衍生物的动力学探讨两大部分。在碳六十衍生物的合成与化学性质探讨中,本论文又分为两个方向去进行研究,第一部分为炔与三级膦以及碳六十的反应探讨;第二部份则是合成具开口碳六十衍生物的探讨。而在碳簇衍生物的动力学探讨中,本论文也分为两个部分,第一部分为具三圆环的碳六十衍生物扩环重排成五圆环碳六十衍生物的动力学研究;第二部分则为内包氢气之具开口碳七十衍生物的氢气释放动力学探讨。 The thesis is devided into two parts, Synthesis and chemical properties of C60 derivatives and the kinetic research of C60 derivatives. In Synthesis and chemical properties of C60 derivatives, the thesis is devided into two directions to study. The first part is the reaction of alkyne、phosphines and C60, the second part is the synthesis of open-caged C60 derivatives. In the second part of the thesis, we discovered that three-member-ring C60 derivatives will rearrange to five-member-ring C60 derivatives spontaneously. We studied the kinetics of the rearrangement of compound 3a、3b. Another project of kinetics study is about the hydrogen released of compound 3e、3f. |
URI: | http://140.113.39.130/cdrfb3/record/nctu/#GT079725530 http://hdl.handle.net/11536/45180 |
显示于类别: | Thesis |