利用雷射光解-時域解析-霍氏轉換紅外光譜法研究六羰基金屬 ( 鉻、鉬、鎢 ) 在環己烷溶液中之反應動力學

完整後設資料紀錄

DC 欄位	值	語言
dc.contributor.author	廖達文	en_US
dc.contributor.author	Ta Wen Liao	en_US
dc.contributor.author	王念夏	en_US
dc.contributor.author	Niann S. Wang	en_US
dc.date.accessioned	2014-12-12T02:21:34Z	-
dc.date.available	2014-12-12T02:21:34Z	-
dc.date.issued	1998	en_US
dc.identifier.uri	http://140.113.39.130/cdrfb3/record/nctu/#NT870500057	en_US
dc.identifier.uri	http://hdl.handle.net/11536/64834	-
dc.description.abstract	我們利用雷射光解-時域解析-霍氏轉換紅外光譜法研究六羰基金屬 ( 鉻、鉬、鎢 ) 與配位基 ( 丙酮、苯、水 ) 在環己烷溶液中之反應動力學。由時域解析-紅外吸收光譜中，測定了不穩定分子：M(CO)5S ( S：環己烷 ) 及 M(CO)5L ( L：丙酮、苯、水 )，在紅外光區之吸收位置及 M(CO)5S 與 L 之反應速率常數，其結果並與文獻值相比較。	zh_TW
dc.description.abstract	Tne kinetics of the reactions of M(CO)6 ( M = Cr、Mo、W ) with ligands ( (CH3)2CO、C6H6、H2O ) in cyclohexane were studied using laser photolysis-time-resolved Fourier transform infrared spectroscopy technique. We have assigned the absorption positions of transient species M(CO)5S ( S = cyclo-C6H12 ) and M(CO)5L ( L = (CH3)2CO、C6H6、H2O ) and determined the absolute rate coefficients for the reactions of M(CO)5S with ligands. Our results were compared with previous studies.	en_US
dc.language.iso	zh_TW	en_US
dc.subject	雷射光解	zh_TW
dc.subject	時域解析-霍氏轉換紅外光譜法	zh_TW
dc.subject	laser photolysis	en_US
dc.subject	time-resolved Fourier transform infrared spectroscopy	en_US
dc.title	利用雷射光解-時域解析-霍氏轉換紅外光譜法研究六羰基金屬 ( 鉻、鉬、鎢 ) 在環己烷溶液中之反應動力學	zh_TW
dc.title	Kinetic Study of the Reactions of M(CO)6 ( M = Cr、Mo、W ) in Cyclohexane using Laser Photolysis-Time-Resolved Fourier Transform Infrared Spectroscopy	en_US
dc.type	Thesis	en_US
dc.contributor.department	應用化學系碩博士班	zh_TW
顯示於類別：	畢業論文