Title: | A novel hydride rearrangement of the acetal group of tetraacetal tetraoxa-cages mediated by Lewis acids |
Authors: | Wu, HJ Chern, JH 交大名義發表 應用化學系 National Chiao Tung University Department of Applied Chemistry |
Issue Date: | 21-Mar-1997 |
Abstract: | Treatment of tetraoxa-cages 1a-f with Lewis acids such as TlC4, AlCl3, BF3 . OEt(2) and MeSO(3)H in dichloromethane at 25 degrees C gives the rearrangement products 2a-f in 90% yields regioselectively and stereoselectively; a novel hydride rearrangement of the acetal group of tetraacetal tetraoxa-cages mediated by Lewis acids. |
URI: | http://dx.doi.org/10.1039/a607403k http://hdl.handle.net/11536/662 |
ISSN: | 1359-7345 |
DOI: | 10.1039/a607403k |
Journal: | CHEMICAL COMMUNICATIONS |
Volume: | |
Issue: | 6 |
Begin Page: | 547 |
End Page: | 548 |
Appears in Collections: | Articles |
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