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dc.contributor.authorOnogi, Chikaoen_US
dc.contributor.authorTorii, Hajimeen_US
dc.contributor.authorHamaguchi, Hiro-oen_US
dc.date.accessioned2014-12-08T15:08:44Z-
dc.date.available2014-12-08T15:08:44Z-
dc.date.issued2009-09-05en_US
dc.identifier.issn0366-7022en_US
dc.identifier.urihttp://dx.doi.org/10.1246/cl.2009.898en_US
dc.identifier.urihttp://hdl.handle.net/11536/6688-
dc.description.abstractThe (13)C and (2)H isotope Substitution effects have been examined for the "Raman spectroscopic signature of life," a mitochondrial Raman band at 1602 cm(-1) that sharply reflects the metabolic activity of living yeast cells. The band shifts to 1542 cm(-1) with (13)C substitution and to 1599 cm(-1) with (2)H substitution. Normal mode analysis based oil a DFT calculation suggests that it originates from a C=C double bond having no hydrogen atoms attached to the carbon atoms. The in-phase C=C stretch mode of ubisemiquinone radicals (CoQ and/or CoQH*) emerges as a strong candidate for the origin of the 1602 cm(-1) band.en_US
dc.language.isoen_USen_US
dc.titleRaman Spectra of Isotope-substituted Mitochondria of Living Budding Yeast Cells: Possible Origin of the "Raman Spectroscopic Signature of Life"en_US
dc.typeArticleen_US
dc.identifier.doi10.1246/cl.2009.898en_US
dc.identifier.journalCHEMISTRY LETTERSen_US
dc.citation.volume38en_US
dc.citation.issue9en_US
dc.citation.spage898en_US
dc.citation.epage899en_US
dc.contributor.department應用化學系zh_TW
dc.contributor.department應用化學系分子科學碩博班zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.contributor.departmentInstitute of Molecular scienceen_US
dc.identifier.wosnumberWOS:000270590500013-
dc.citation.woscount13-
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