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dc.contributor.authorZhu, Chaoyuanen_US
dc.contributor.authorLiang, Kuo Kanen_US
dc.contributor.authorHayashi, Michitoshien_US
dc.contributor.authorLin, Sheng Hsienen_US
dc.date.accessioned2014-12-08T15:09:45Z-
dc.date.available2014-12-08T15:09:45Z-
dc.date.issued2009-03-30en_US
dc.identifier.issn0301-0104en_US
dc.identifier.urihttp://dx.doi.org/10.1016/j.chemphys.2009.01.006en_US
dc.identifier.urihttp://hdl.handle.net/11536/7459-
dc.description.abstractIt is well-known that the mirror image between absorption and fluorescence spectra is held for the displaced harmonic-oscillator system, and also this mirror image is independent to the chiral symmetry in which the excited-state potential energy surface is right-handed or left-handed with respect to the ground-state potential energy surface. As the first-order approximation of anharmonic correction is added into the displaced harmonic oscillator, this mirror image is broken down, and then the spectra can be depended on the chiral symmetry mentioned above. Both absorption and fluorescence coefficients are derived analytically within the first-order anharmonic approximation and numerical test is carried out to demonstrate the breaking down of the mirror image. Based on the same analysis, the electron transfer rate is derived analytically within the first-order anharmonic approximation. This rate might take the form of Arrhenius's equation but not form of Marcus's equation. Furthermore, it is found that this rate is also depending on the chiral symmetry. (c) 2009 Elsevier B.V. All rights reserved.en_US
dc.language.isoen_USen_US
dc.subjectAnharmonic effecten_US
dc.subjectMirror imageen_US
dc.subjectAbsorption spectraen_US
dc.subjectFluorescence spectraen_US
dc.subjectElectron transferen_US
dc.titleTheoretical treatment of anharmonic effect on molecular absorption, fluorescence spectra, and electron transferen_US
dc.typeArticleen_US
dc.identifier.doi10.1016/j.chemphys.2009.01.006en_US
dc.identifier.journalCHEMICAL PHYSICSen_US
dc.citation.volume358en_US
dc.citation.issue1-2en_US
dc.citation.spage137en_US
dc.citation.epage146en_US
dc.contributor.department應用化學系分子科學碩博班zh_TW
dc.contributor.departmentInstitute of Molecular scienceen_US
dc.identifier.wosnumberWOS:000265005300022-
dc.citation.woscount13-
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