標題: | Three-Component and Nonclassical Reaction of Phosphines with Enynes and Aldehydes: Formation of gamma-Lactones Featuring alpha-Phosphorus Ylides |
作者: | Deng, Jie-Cheng Chuang, Shih-Ching 應用化學系 Department of Applied Chemistry |
公開日期: | 6-五月-2011 |
摘要: | Inverted carbenoid species, generated from attack of phosphines at the alpha(delta')-carbon of hex-2-en-4-ynedioic acid dialkyl esters, react with aldehydes to give gamma-lactones possessing an alpha-phosphorus ylide moiety. |
URI: | http://dx.doi.org/10.1021/ol200527t http://hdl.handle.net/11536/8876 |
ISSN: | 1523-7060 |
DOI: | 10.1021/ol200527t |
期刊: | ORGANIC LETTERS |
Volume: | 13 |
Issue: | 9 |
起始頁: | 2248 |
結束頁: | 2251 |
顯示於類別: | 期刊論文 |