標題: Observation of transition state in Raman triggered oxidation of chloroform in the ground state by real-time vibrational spectroscopy
作者: Iwakura, Izumi
Yabushita, Atsushi
Kobayashi, Takayoshi
電子物理學系
Department of Electrophysics
公開日期: 27-五月-2008
摘要: A transition state (TS) during Raman triggered oxidation of chloroform was directly observed by ultrafast spectroscopy using broadband visible sub-5 fs pulses. Changes in the molecular structures including the TSs along the reaction pathways were detected by the time-dependent instantaneous frequencies of vibrational modes. The Raman triggered oxidation of chloroform was found to be initiated by the excitation of vibrational levels through stimulated Raman processes involving the ground-state chloroform oxygen complex. (C) 2008 Published by Elsevier B.V.
URI: http://dx.doi.org/10.1016/j.cplett.2008.03.003
http://hdl.handle.net/11536/9320
ISSN: 0009-2614
DOI: 10.1016/j.cplett.2008.03.003
期刊: CHEMICAL PHYSICS LETTERS
Volume: 457
Issue: 4-6
起始頁: 421
結束頁: 426
顯示於類別:期刊論文


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