Nickel promoted switchable hydroheteroarylation of cyclodienes via C-H bond activation of heteroarenes

doi:10.1016/j.tet.2015.03.066

Full metadata record

DC Field	Value	Language
dc.contributor.author	Lee, Wei-Chih	en_US
dc.contributor.author	Shih, Wei-Chin	en_US
dc.contributor.author	Wang, Ting-Hsuan	en_US
dc.contributor.author	Liu, Yuhua	en_US
dc.contributor.author	Yap, Glenn P. A.	en_US
dc.contributor.author	Ong, Tiow-Gan	en_US
dc.date.accessioned	2015-12-02T02:59:10Z	-
dc.date.available	2015-12-02T02:59:10Z	-
dc.date.issued	2015-07-01	en_US
dc.identifier.issn	0040-4020	en_US
dc.identifier.uri	http://dx.doi.org/10.1016/j.tet.2015.03.066	en_US
dc.identifier.uri	http://hdl.handle.net/11536/127880	-
dc.description.abstract	We demonstrated Ni-catalyzed switchable hydroheteroarylation of cyclic dienes via C-H bond activation of heteroarenes. In the presence of an N-heterocyclic carbene (NHC) ligand, hydroheteroarylation of cyclic diene with azole afforded alpha-alkenyl-azole, forging a Heck-like product without using any external oxidant. Conversely, changing the ligand to PCy3 would switch this reaction manifold to afford the other isomeric beta-alkenyl substituted azole. (C) 2015 Elsevier Ltd. All rights reserved.	en_US
dc.language.iso	en_US	en_US
dc.subject	Selective CH bond activation	en_US
dc.subject	Nickel	en_US
dc.subject	Hydroheteroarylation	en_US
dc.subject	Cyclic diene	en_US
dc.title	Nickel promoted switchable hydroheteroarylation of cyclodienes via C-H bond activation of heteroarenes	en_US
dc.type	Article	en_US
dc.identifier.doi	10.1016/j.tet.2015.03.066	en_US
dc.identifier.journal	TETRAHEDRON	en_US
dc.citation.volume	71	en_US
dc.citation.issue	26-27	en_US
dc.citation.spage	4460	en_US
dc.citation.epage	4464	en_US
dc.contributor.department	應用化學系	zh_TW
dc.contributor.department	Department of Applied Chemistry	en_US
dc.identifier.wosnumber	WOS:000356207700008	en_US
dc.citation.woscount	0	en_US
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