標題: Effect of Ti substitution on the electrochemical properties of LaCr1-x Ti (x) O3+0.5x (x=0-0.15)
作者: Hao, Chia-Kan
Tsai, Chia-Fen
Lee, Chi-Shen
應用化學系
Department of Applied Chemistry
關鍵字: Perovskite;SOFC;LaCrO3;Ionic conductivity;Electronic conductivity;Impedance spectra
公開日期: May-2016
摘要: Perovskite compound LaCr1-x Ti (x) O3+0.5x (x = 0-0.15) was synthesized from an EDTA-chelating precursor solution at T < 800 A degrees C, a temperature lower than that of the conventional solid-state method. Structural properties were determined at room temperature using X-ray powder diffraction and the lattice parameter decreased with increasing proportion of Ti. LaCr1-x Ti (x) O3+0.5x was chemically stable under a H-2 atmosphere at 900 A degrees C. Both electrical and ionic conductivity increased with increasing proportion of doped Ti, indicative of a p-type semiconductor. An Arrhenius-like behavior was observed, and the optimized bulk electrical conductivity was 0.107 S cm(-1) for LaCr0.85Ti0.15O3.075 at 850 A degrees C. X-ray photoelectron spectra indicate that the effect of the concentration of charge carrier on conductivity is closely related to the oxidation states of ions. The maximum power density reaches as high as 210 mW cm(-2) at 800 A degrees C for SOFC with LaCr1-x Ti (x) O3+0.5x (x = 0.15) anode. Ti-substituted perovskite materials LaTi (x) Cr1-x O3+0.5x (x = 0-0.15) show enhanced electronic and ionic conductivity with increasing proportion of doped Ti. [GRAPHICS]
URI: http://dx.doi.org/10.1007/s10971-015-3951-6
http://hdl.handle.net/11536/133411
ISSN: 0928-0707
DOI: 10.1007/s10971-015-3951-6
期刊: JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
Volume: 78
Issue: 2
起始頁: 394
結束頁: 402
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