標題: Pure rotational spectrum of HCI
作者: Nakajima, Masakazu
Endo, Yasuki
應用化學系
Department of Applied Chemistry
關鍵字: Pure rotational transitions;HCI;Monohalomethylene;Monohalocarbene
公開日期: 1-Aug-2019
摘要: The 1(01)-0(00) and 2(02)-1(01) rotational transitions of a monohalomethylene, HCI, are observed in a discharge plasma of diiodomethane by Fourier-transform microwave (FTMW) and FTMW-microwave double-resonance spectroscopy. The effective rotational constant (B + C)/2, the centrifugal distortion constant Delta(J), and the quadrupole coupling constant of the iodine nucleus are determined from the observed line frequencies. The nuclear spin-rotation coupling constant C-bb is required to be included into the set of fitting parameters for a satisfactory analysis of the observed line frequencies. (C) 2019 Elsevier Inc. All rights reserved.
URI: http://dx.doi.org/10.1016/j.jms.2019.05.008
http://hdl.handle.net/11536/152691
ISSN: 0022-2852
DOI: 10.1016/j.jms.2019.05.008
期刊: JOURNAL OF MOLECULAR SPECTROSCOPY
Volume: 362
起始頁: 25
結束頁: 28
Appears in Collections:Articles