Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Weng, Sheng-Feng | en_US |
dc.contributor.author | Wang, Yun-Hsin | en_US |
dc.contributor.author | Lee, Chi-Shen | en_US |
dc.date.accessioned | 2014-12-08T15:21:50Z | - |
dc.date.available | 2014-12-08T15:21:50Z | - |
dc.date.issued | 2012-04-01 | en_US |
dc.identifier.issn | 0022-4596 | en_US |
dc.identifier.uri | http://dx.doi.org/10.1016/j.jssc.2012.01.046 | en_US |
dc.identifier.uri | http://hdl.handle.net/11536/15535 | - |
dc.description.abstract | Two novel materials, [M(C6H5O7)(C6H6O7)(C6H7O7)(H2O)] center dot H2O (M=La(1a), Ce(1b)) and [Ce-2(C2O4) (C6H6O7)(2)] center dot 4H(2)O (2), with a metal-organic framework (MOF) were prepared with hydrothermal reactions and characterized with photoluminescence, magnetic susceptibility, thermogravimetric analysis and X-ray powder diffraction in situ. The crystal structures were determined by single-crystal X-ray diffraction. Compound 1 crystallized in triclinic space group P (1) over bar (No. 2); compound 2 crystallized in monoclinic space group P2(1)/c (No. 14). The structure of 1 is built from a 1D MOF, composed of deprotonated citric ligands of three kinds. Compound 2 contains a 2D MOF structure consisting of citrate and oxalate ligands; the oxalate ligand arose from the decomposition in situ of citric acid in the presence of Cu-II ions. Photoluminescence spectra of compounds 1b and 2 revealed transitions between the 5d(1) excited state and two levels of the 4f(1) ground state (F-2(5/2) and F-2(7/2)). Compounds 1b and 2 containing Ce-III ion exhibit a paramagnetic property with weak antiferromagnetic interactions between the two adjacent magnetic centers. (C) 2012 Elsevier Inc. All rights reserved. | en_US |
dc.language.iso | en_US | en_US |
dc.subject | Rare earth | en_US |
dc.subject | Copper | en_US |
dc.subject | Citric acid | en_US |
dc.subject | Oxalate | en_US |
dc.subject | Hydrothermal | en_US |
dc.subject | Metal organic framework | en_US |
dc.title | New metal-organic frameworks of [M(C6H5O7)(C6H6O7)(C6H7O7)(H2O)] center dot H2O (M=La, Ce) and [Ce-2(C2O4)(C6H6O7)(2)] center dot 4H(2)O | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1016/j.jssc.2012.01.046 | en_US |
dc.identifier.journal | JOURNAL OF SOLID STATE CHEMISTRY | en_US |
dc.citation.volume | 188 | en_US |
dc.citation.issue | en_US | |
dc.citation.spage | 77 | en_US |
dc.citation.epage | 83 | en_US |
dc.contributor.department | 應用化學系 | zh_TW |
dc.contributor.department | Department of Applied Chemistry | en_US |
dc.identifier.wosnumber | WOS:000301610400012 | - |
dc.citation.woscount | 6 | - |
Appears in Collections: | Articles |
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