標題: Tuning Reactivity of Glycosyl Imidinium Intermediate for 2-Azido-2-deoxyglycosyl Donors in alpha-Glycosidic Bond Formation
作者: Ingle, Arun B.
Chao, Chin-Sheng
Hung, Wei-Cheng
Mong, Kwok-Kong Tony
應用化學系
Department of Applied Chemistry
公開日期: 18-Oct-2013
摘要: The chemical properties of nucleophile additives were investigated in a modulated glycosylation context. N-Formylmorpholine (NFM) was found to be an effective modulator for glycosylation with less reactive 2-azido-2-deoxythioglucosyl and thiogalactosyl donors.
URI: http://dx.doi.org/10.1021/ol402519c
http://hdl.handle.net/11536/22974
ISSN: 1523-7060
DOI: 10.1021/ol402519c
期刊: ORGANIC LETTERS
Volume: 15
Issue: 20
起始頁: 5290
結束頁: 5293
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