標題: | A novel photoinduced ring opening and isomerization of adamantane-2-spiro isoxazolines using MO(CO)(6) |
作者: | Senthilvelan, Annamalai Lee, Gene-Hsiang Chung, Wen-Sheng 應用化學系 Department of Applied Chemistry |
關鍵字: | adamantane isoxazolines;photorearrangement;isomerization;enaminoketones |
公開日期: | 2-Oct-2006 |
摘要: | The MO(Co)(6)-mediated photoinduced ring-opening reactions of adamantane isoxazolines involve novel rearrangement that provide enaminoketones as major products and beta-hydroxy ketones as minor ones; in contrast, only beta-hydroxy ketones and alpha,beta-unsaturated ketones were obtained under thermal condition. (c) 2006 Elsevier Ltd. All rights reserved. |
URI: | http://dx.doi.org/10.1016/j.tetlet.2006.07.156 http://hdl.handle.net/11536/11687 |
ISSN: | 0040-4039 |
DOI: | 10.1016/j.tetlet.2006.07.156 |
期刊: | TETRAHEDRON LETTERS |
Volume: | 47 |
Issue: | 40 |
起始頁: | 7179 |
結束頁: | 7183 |
Appears in Collections: | Articles |
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