標題: | Chemoselective deprotection of acid labile primary hydroxyl protecting groups under CBr4-photoirradiation conditions |
作者: | Chen, MY Patkar, LN Lu, KC Lee, ASY Lin, CC 應用化學系 Department of Applied Chemistry |
關鍵字: | CBr4-photoirradiation;deprotection |
公開日期: | 6-十二月-2004 |
摘要: | The CBr4-photoirradiation in methanol generates a controlled source of HBr, which can chemoselectively deprotect commonly used hydroxyl-protecting groups in saccharides and nucleosides, such as tert-butyldimethylsilyl, isopropylidene, benzylidene and triphenyl ethers in the presence of other acid-labile functional groups. (C) 2004 Elsevier Ltd. All rights reserved. |
URI: | http://dx.doi.org/10.1016/j.tet.2004.09.095 http://hdl.handle.net/11536/25557 |
ISSN: | 0040-4020 |
DOI: | 10.1016/j.tet.2004.09.095 |
期刊: | TETRAHEDRON |
Volume: | 60 |
Issue: | 50 |
起始頁: | 11465 |
結束頁: | 11475 |
顯示於類別: | 期刊論文 |