標題: | 3-SUBSTITUTED 2-CYCLOPENTENONES FROM CYCLOPENTADIENES |
作者: | LIN, CC HSIA, KS WU, HJ 應用化學系 Department of Applied Chemistry |
關鍵字: | 3-SUBSTITUTED 2-CYCLOPENTENONES;CYCLOPENTADIENES;PCC |
公開日期: | 1-Dec-1993 |
摘要: | Oxidation of cyclopentadienes 1a-1j, which were prepared by alkylation of cyclopentadienyl anion with the corresponding alkyl bromides, with pyridinium chlorochromate (PCC) gave the 2-cyclopentenones 2a-2j respectively in 10-15% yields. Reaction of 3 and 5 with PCC gave the spiro compounds 4 and 6 respectively in 75-80% yields. |
URI: | http://hdl.handle.net/11536/2754 |
ISSN: | 0009-4536 |
期刊: | JOURNAL OF THE CHINESE CHEMICAL SOCIETY |
Volume: | 40 |
Issue: | 6 |
起始頁: | 587 |
結束頁: | 591 |
Appears in Collections: | Articles |