含式雙苯乙烯及雙苯乙炔液晶基之側鏈液晶聚環氧丙烷之合成

Abstract

本研究之主要目的是合成出含反式雙苯乙烯及雙苯乙炔之環氧丙烷及其側 鏈液晶聚合物，此兩系列環氧丙烷化合物，都以Boron trifloride ether complex作為起始劑，進行開環聚合反應，合成出以環氧丙烷為高 分子主鏈之新型側鏈液晶聚合物。 Presenting the synthesis and characterization of side-chain liquid crystalline polyoxetaines containing trans-stilbene and 4-methoxytolane side groups is the goal of this study. The prepared oxetane monomers using Boron trifloride ether complex as a initiator to form new side-chain liquid crystalline polymers.